A technical characterization of Roman plasters, Luxor temple, Upper Egypt

Part of : Mediterranean archaeology & archaeometry : international journal ; Vol.12, No.2, 2012, pages 81-93

Issue:
Pages:
81-93
Section Title:
Articles
Author:
Abstract:
The present paper aims to characterize some Roman plasters from the reign of the Emperor Diocletian in the late 3rd century AD. These plasters were applied over Pharaonic walls from the reign of Amenhotep III (c.1402–1364 BC) at Luxor temple, Upper Egypt. For the characterization of theses plasters, several analytical techniques were applied such as optical microscopy (OM), scanning electron mi-croscopy (SEM) equipped with an energy dispersive X-ray detector (EDS), X-ray powder diffraction analysis (XRPD), micro-Raman and Fourier transform infrared spectroscopies (μ-Raman and FT–IR). Based on the results of these analyses, the stratigraphic structure of the plaster layers was identified as fine coat ‘intonaco’ which is based mainly on lime and coarse coat ‘arriccio’ which consists of silica sand, phases of calcium carbonates and different pozzolanic additives. Moreover, the results revealed the green pigment as green earth (celadonite), the red pigment as red ochre, the yellow pigment as yellow ochre and the white pigment as calcium carbonate. The obtained data helped in improving our knowledge of some materials used during the Roman age in Egypt.
Subject:
Subject (LC):
Keywords:
Roman plasters, Luxor temple, XRPD, SEM−EDS, μ-Raman, FT–IR
Notes:
Corresponding autho Hussein Marey Mahmoudr: (marai79@hotmail.com), The authors are grateful to Mr. S. Oikonomidis, School of Geology, Aristotle University for his support through the SEM study. Special thanks are due to Mr. S. Haralampos and to Mr. Th. Dimitriadis, Department of Inorganic Chemistry, Aristotle University for their assistance in the study using FT-IR spectroscopy.
References (1):
  1. Adam, J-P (2005) roman Building: Materials and Techniques, Translated by Anthony Mathews, Taylor & Francis e-Library.Adriaens, A., and Dowsett, M.G. (2004) Electron microscopy and its role in cultural heritage stuies. In: Janssens, K and Van Grieken, R. (Eds.), Comprehensive Ana-lytical Chemistry, Vol. XLii "Non-destructive Microanalysis of Cultural Heritage Materials, Elsevier, 73–124.Aliatis, I., Bersani, D., Campani, E., Casoli, A., Lottici, P.P., Mantovan, A., Marino, I-G., Ospitali, F. (2009) Green pigments of the Pompeian artists’ palette, spectrochimica Acta A, Vol. 73, 532–538.Ali, M.F. (2003) Comparison study of Blue and green pigments from the third intermediate period till the Greek Roman Period, egyptian Journal of Analytical Chemistry, Vol.12, 21–30Baraldi, P., Bonazzi, A., Gioedani, N., Paccagnella, F., and Zannini, P. (2006) Analytical characterization of Roman plasters of the ‘domus Farini’ in Modena, Archaeometry, Vol. 48, 481–99.Bearat, H., and Pradell, T. (1997) Contribution of Mössbauer Spectroscopy to the study of Ancient Pigments and Paintings. In: Béarat, H., Fuchs, M., Maggetti, M and Paunier, D. (Eds.), roman Wall Painting: materials, techniques, analysis and conservation, Proceedings of the international Workshop, Fribourg, Institute of Mineralogy and Petrography, University of Fribourg, 239–256.Berry, M (1999) A study of pigments from a Roman Egyptian shrine, AiCCM Bulletin, 1–9.Bikiaris, D., Daniilia Sr., Sotiropoulou, S., Katsimbiri, O., Pavlidou, E., Moutsatsou, A.P., Chryssoulakis, Y. (1999) Ochre differentiation through micro-Raman and micro-FTIR Spectroscopes: application on wall paintings at Meteora and Mount Athos, Greece, spectrochimica Acta A, Vol. 56, 3–18.Bläuer-Böhm, Ch., and Jägers, E. (1996) Analysis and recognition of dolomitic lime mortars, in Proceedings of the international Workshop on roman Wall Painting, roman Wall Painting Materials, Techniques, Analysis and Conservation, Fribourg, March 7–9, 1996 (eds. H. Béarat, M. Fuchs, M. Maggetti and D. Paunier), 223–35, Institute of Mineralogy and Petrology, Fribourg University. Casellato, U., Vigato, P.A., Russo, U., Matteini, M. (2000) A Mössbauer Approach to the Physico-Chemical Characterization of Iron-Containing Pigments for Historical Wall Paintings, Journal of Cultural Heritage, Vol. 1, 217–232.Castriota, M., Cosco, V., Barone, T., De Santo, G., Carafa, P., and Cazzanelli, E. (2008) Micro-Raman characterizations of Pompei’s mortars, Journal of raman spectroscopy, Vol. 39(2), 295–301.Duran, A., Jimenez De Haro, M. C., Perez-Rodriguez, J. L., Franquelo, M. L., Herrera, L. K., and Justo, A. (2010) Determination of pigments and binders in Pompeian paintings using synchrotron radiation – high-resolution X-ray power diffraction and conventional spectroscopy–chromatography, Archaeometry, Vol. 52, 286–307.El Goresy, A., Jaksch, H., Abdel Razek, M., Weiner, K.L. (1986) Ancient pigments in wall paintings of Egyptian tombs and temples: an archaeometric project, Preprint of the Max Planck Institute of Nuclear Physics MPI H- V 12, Heidelberg.El Goresy, A. (2000) Polychromatic Wall Painting Decorations in Monuments of Pharaonic Egypt: compositions, chronology and painting techniques, Proceedings of the First international symposium: "The Wall Paintings of Thera", Sherratt, S. (ed.), Vol. I, Petros M. Nomikos and Thera Foundation, Piraeus, Athens, Hellas, 49–70.Franquelo, M. L., Robador, M. D., Ramírez-Valle, V., Durán, A., Jiménez de Haro, M. C., and Pérez-Rodríguez, J. L. (2008) Roman ceramics of hydraulic mortars used to build the Mithraeum house of Mérida (Spain), Journal of Thermal Analysis and Calorimetry, Vol. 92 (1), 331–5.Franquelo, M.L., Duran, A., Herrera, L.K., Jimenez de Haro, M.C., Perez- Rodriguez, J.L. (2009) Comparison between micro-Raman and micro-FTIR spectroscopy techniques for the characterization of pigments from Southern Spain Cultural Heritage, Journal of Molecular structure, Vol. 924-926, 404–412.Genestar, J.C., Bonafé, C.P. (2004) The use of natural earths in picture: study and differentiation by thermal analysis, Thermochimica Acta, Vol. 413, 185–192.Hradil, D. Grygar T., Hradilova, J. Bezdička, P. (2003) Clay and iron oxide pigments in the history of painting, Applied Clay science, Vol. 22, 223–236Kamil, J (1976) LUXOR: A Guide to Ancient Thebes, (2nd ed.), London.Katsaros, T, Liritzis, I and Laskaris, N (2011) Identification of Theophrastus’ pigments egyptios kyanos and psimythion from archaeological excavations: A case study. Archaeosciences (revue d’Archaeometrie) 34, 69–80.Lee, L., Quirke, S (2001) Painting materials. In: Nicholson, T.P and Shaw, I. (Eds.), Ancient egyptian materials and Technology, UK, 104–119.Mazzocchin, G. A., Agnoli, F., and Salvadori, M. (2004), Analysis of Roman age wall paintings, Talanta, Vol. 64, 732–741.Mazzocchin, G. A., Orsega, E. F., Baraldi, P., and Zannini, P. (2006) Aragonite in Roman wall paintings of the VIIIa Regio, Aemilia, and Xa Regio, Venetia Et Histria, Annali di Chimica, Vol. 96 (7–8), 377–387.Mazzocchin, G. A., Del Faveroi, M., and Tasca, G. (2007) Analysis of pigments from Roman wall paintings in the ‘Agro Centuriato’ of Julia Concordia (Italy), Annali di Chimica, Vol. 97, 905–913.Mazzocchin, G. A., Vianello, A., Minghelli, S., and Rudello, D. (2010) Analysis of Roman wall paintings from the Thermae of ‘Iulia Concordia’, Archaeometry, Vol. 52, 644–655.Mirti, P., Appolonia, L., Casoli, A., Ferrari, R.P., Lurenti, E., Amisano Canesi, A., Chiari, G. (1995) Spectrochemical and Structural Studies on a Roman Sample of Egyp-tian blue, spectrochimica Acta A, Vol. 51 (3), 437–446.Ortega, M., Ascencio, J.A., San-Germán, C.M., Fernándes, M.E. (2001) Analysis of Prehistoric Pigments from “Templo Mayor” of Mexico City, Journal of Materials science, Vol. 36, 751–756.Ospitali, F., Bersani, D., Di Lonardo, G., Lottici, P.P.(2008) ‘Green earths’: vibrational and elemental characterization of glauconites, celadonites and historical pigments, Journal of raman spectroscopy, Vol. 39, 1066–1073.Siddall, R. (2006) Not a day without a line drawn: Pigments and painting techniques of Roman Artists, infocus magazine, Proceedings of the royal Microscopy society, issue 2, 19–31.Velosa, L.A, Coroado, J., Veiga, R.M., Rocha, F. (2007) Characterisation of roman mortars from Conímbriga with respect to their repair, Materials Characterization, Vol. 58 (11-12), 1208–1216.Vitruvius (1960) The ten books on architecture Vii, transl. N. H. Morgan, 1st THUS edn, Dover Publications, NewYorkWainwright, I.N.M., Moffatt, E.A., Sirois, P.J. (2009) Occurrences of green earth pig-ments on northwest coast first nations painted objects, Archaeometry, Vol. 51, 440–456.Zorba, T., Pavlidou, E., Stanojlovic, M., Bikiaris, D., Paraskevopoulos, K.M., Nikolic, V., Nikolic, P.M. (2006) Technique and palette of XIIIth century painting in the monastery of Mileseva, Applied Physics A, Vol. 83, 719–725.